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ANITA (Analysing Interferometer for Ambient Air) is a flight experiment precursor for a permanent continuous air quality monitoring system on the ISS (International Space Station). For the safety of the crew, ANITA can detect and quantify quasi-online and simultaneously 33 gas compounds in the air with ppm or sub-ppm detection limits. The autonomous measurement system is based on FTIR (Fourier Transform Infra-Red spectroscopy). The system represents a versatile air quality monitor, allowing for the first time the detection and monitoring of trace gas dynamics, with high time resolution, in a spacecraft atmosphere. ANITA operated on the ISS from September 2007 to August 2008. This paper summarises the results of ANITA's air analyses and compares results to other measurements acquired on ISS during the operational period.

The photocatalytic oxidation of VOCs was investigated using a novel countercurrent flow reactor designed to enable the treatment of toluene present in the gas and the aqueous phases simultaneously. The reactor was packed with silica-titania composites commingled with plastic pall rings. Using this mixed packing style was advantageous as it resulted in a higher UV penetration throughout the reactor. The average UV intensity in the reactor was determined to be 220 μW/g irradiated TiO2. It was found that under dry conditions, the STCs had a high adsorption capacity for toluene; however, this adsorption was completely hindered by the wetting of the STCs when the two phases were flowing simultaneously. The destruction of toluene in the aqueous phase was determined to follow a linear trend as a function of the contaminant concentration.

Compliance with tighter emission regulations has increased the proportion of parasitic weight in commercial vehicles. In turn, the amount of payload must be reduced to comply with transportation weight requirements. A re-design of commercial vehicle components is necessary to decrease the vehicle weight and improve payload capacity. Side rails have traditionally been manufactured from high strength steels, but significant weight reductions can be achieved by substituting steel side rails with 6013 high strength aluminum alloy side rails. Material and stress analyses are presented in this paper in order to understand the effect of manufacturing process on the material's mechanical behavior. Metallographic and tensile test experiments for the 6013-T4 alloy were performed in preparation for residual stress measurements of a punching operation. Punched holes are critical to the function of the side rail and can lead to high stress levels and cracking.

With the growing environmental concerns, biodegradable materials are gaining more importance. Biocomposites which are made from a combination of biological fiber such as flax and hemp together with plastics are finding a good number of applications in day to day life. Flax has good physical and mechanical properties that can be utilized in areas like construction, biomedical & bioproducts and electronics applications. The quality of fiber depends upon various unit operations used in the processing. Drying is one of the most important unit operations which significantly affect the quality of the fiber. The method of drying for removal of moisture from the fiber significantly affects the drying time and quality. In the present study the raw flax fiber was subjected to drying before and after chemical treatment. The physical properties such as; tensile strength, color and structural changes were measured for raw and chemically treated flax fibers.

The physical and optical properties viz., water absorption pattern, density, color and opacity of oil palm fiber-LLDPE composites were studied. The effect of fiber size, fiber loading and fiber treatment on the above parameters was also studied. Alkali treatment on fibers was done to reduce the hydrophilic nature of composites. It was found that the water absorption in most of the combinations followed typical fickian behavior. The rate of water absorption and swelling increased with fiber loading. However alkali treatment on fibers resulted in reduction of water absorption at higher fiber loading only and composites with higher fiber size exhibited higher water absorption. True density of oil palm fiber-LLDPE composites were in the range of 967-1177 kg m-₃, whereas the bulk density ranged from 942-1122 kg m-₃. The dielectric constant of the composite was in the range of 3.22 to 6.73.

The research on using natural fibres as the reinforcement in plastic composites has increased dramatically in the last few years. Flax fibres are renewable resources with low specific mass, reduced energy consumption, and relatively low in cost. These advantages make flax fibres recognized as a potential replacement for glass fibres in composites. Among plastic, polyethylene was concluded to be a suitable material used as matrix in natural fibre reinforced biocomposites. However there are few studies on this area so far. In this paper, the processing method of flax fibre-reinforced polyethylene biocomposites is introduced. Flax fibre polyethylene biocomposite consists of flax fibre as the reinforcing component and high density polyethylene as the matrix. Acrylic acid pre-treatment was applied to flax fibre to improve the bonding between fibre and polyethylene.

The properties of oil palm fiber were estimated and compared with oil seed flax and industrial hemp fibers. Biocomposite of oil palm fiber and linear low density polyethylene (LLDPE) was manufactured. The effect of fiber size, fiber content and fiber treatment on dimensional stability of the biocomposite was studied. The true density of oil palm fiber is found to be 1503 kg m-₃. The oil palm fibers obtained from field contained nearly one-fourth impurities, and the equilibrium moisture contents (EMC) values of fibers nearly doubled with 25% increase in relative humidity. The dielectric constant of oil palm fiber was in the range of 7.76-8.31. The oil palm fiber resulted in thermograms with two endothermic peaks and three exothermic peaks with the first degradation temperature at 301.71°C. Alkali treatment reduced first degradation temperature to 297.1°C.

Biodiesel-blended fuel is increasingly becoming available for diesel engines. Due to seasonal and economic factors, biodiesel available in filling stations can be sourced from varying feedstocks. Moreover, biodiesel may not contain the minimum oxidative stability required by the time it is used by the automotive consumer. With fuel dilution of engine oil accelerated by post-injection of fuel for regeneration of diesel particulate filters, it is necessary to investigate whether different biodiesel feedstocks or stabilities can affect engine oil properties. In this work, SAE 15W-40 CJ-4 is diluted with B20 fuel, where the B20 was prepared with soy methyl ester (SME) B100 with high Rancimat oxidative stability, SME B100 with low oxidative stability, and lard methyl ester (LME). The oils were then subjected to laboratory aging simulating severe drive cycles. At intermediate aging times, samples were obtained and additional B20 was added to simulate on-going fuel dilution.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Homogeneous Charge Compression Ignition (HCCI) engine technology has been an area of rapidly increasing research interest for the past 15 years and appears poised for commercialisation through the efforts of international research institutions and manufacturers alike. In spite of significant worldwide research efforts on numerous aspects of this technology, the need still exists for accurate and computationally efficient fuel auto-ignition models capable of predicting the heat release dynamics of two-stage auto-ignition, especially for full boiling range fuels, sensitive to the effects of pressure, temperature, fuel equivalence ratio and inert dilution.

The US Army is currently assessing the feasibility and defining the requirements of a Single Common Powertrain Lubricant (SCPL). This new lubricant would consist of an all-season (arctic to desert), fuel-efficient, multifunctional powertrain fluid with extended drain capabilities. As a developmental starting point, diesel engine testing has been conducted using the current MIL-PRF-46167D arctic engine oil at high temperature conditions representative of desert operation. Testing has been completed using three high density military engines: the General Engine Products 6.5L(T) engine, the Caterpillar C7, and the Detroit Diesel Series 60. Tests were conducted following two standard military testing cycles; the 210 hr Tactical Wheeled Vehicle Cycle, and the 400 hr NATO Hardware Endurance Cycle. Modifications were made to both testing procedures to more closely replicate the operation of the engine in desert-like conditions.

Initial results are presented for the production of hydrogen from waste lubricating oil using a chemical looping reforming (CLR) process. The development of flexible and sustainable sources of hydrogen will be required to facilitate a "hydrogen economy." The novel CLR process presented in this paper has an advantage over hydrogen production from conventional steam reforming because CLR can use complex, low value, waste oils. Also, because the process is scalable to small and medium size, hydrogen can be produced close to where it is required, minimizing transport costs. Waste lubricating oil typically contains 13-14% weight of hydrogen, which through the steam reforming process could produce a syngas containing around 75 vol% H₂, representing over 40 wt% of the fuel. The waste oil was converted to a hydrogen-rich syngas in a packed bed reactor, using a Ni/ Al₂O₃ catalyst as the oxygen transfer material (OTM).

Existing gasoline DI injection equipment has been modified to generate single hole pulsed gas jets. Injection experiments have been performed at combinations of 3 different pressure ratios (2 of which supercritical) respectively 3 different hole geometries (i.e. length to diameter ratios). Injection was into a pressure chamber with optical access. Injection pressures and injector hole geometry were selected to be representative of current and near-future DI natural gas engines. Each injector hole design has been characterized by measuring its discharge coefficient for different Re-levels. Transient jets produced by these injectors have been visualized using planar laser sheet Mie scattering (PLMS). For this the injected gas was seeded with small oil droplets. The corresponding flow field was measured using particle image velocimetry (PIV) laser diagnostics.

The application of accelerated catalyst aging procedures on an engine dynamometer test bed for the purpose of demonstrating catalyst durability is examined. A proof-of-principle approach is followed using catalysts from vehicles certified to U.S. Tier 2 Bin 4 and California SULEV 2 levels. Accelerated durability demonstration methods based upon conventional fuel cut cycles were employed to age catalysts to levels predicted by quantification of thermal catalyst bed severity on the Standard Road Cycle (SRC) relative to the fuel cut aging cycle using the Bench Aging Time (BAT) equation. Emissions deterioration on the accelerated aging cycle is compared to the automobile manufacturers' certification values and to whole vehicle emissions performance results from several different in-use vehicle fleets. The influence of technology on whole vehicle emissions levels and deterioration characteristics is also evaluated.

In this paper, the microstructure-based finite element modeling method is used in investigating the loading path dependence of formability of transformation induced plasticity (TRIP) steels. For this purpose, the effects of different loading path on the forming limit diagrams (FLD) of TRIP steels are qualitatively examined using the representative volume element (RVE) of a commercial TRIP800 steel. First, the modeling method was introduced, where a combined isotropic/kinematic hardening rule is adopted for the constituent phases in order to correctly describe the cyclic deformation behaviors of TRIP steels during the forming process with combined loading paths which may include the unloading between the two consecutive loadings. Material parameters for the constituent phases remained the same as those in the authors' previous study [ 1 ] except for some adjustments for the martensite phase due to the introduction of the new combined hardening rule.

Predicting AHSS cracking during crash events and forming processes is an enabling technology for AHSS application. Several fracture criteria including MatFEM and Modified Mohr-Coulomb Criterion were developed recently. However, none of them are designed to cover more fracture modes such as bending fracture and tearing fracture with initial damage. A mixed-mode fracture criterion (MMFC) is proposed and developed to capture multiple fracture modes including in-plane shearing fracture, cross-thickness shearing fracture with bending effect and tearing fracture with initial damage. The associated calibration procedure for this criterion is developed. The criterion is implemented in a commercial FEA code and several lab validations are conducted. The results show its promising potential to predict AHSS cracking at large strain conditions.

Advanced High Strength Steels (AHSS) have been implemented in the automotive industry to balance the requirements for vehicle crash safety, emissions, and fuel economy. With lower ductility compared to conventional steels, the fracture behavior of AHSS components has to be considered in vehicle crash simulations to achieve a reliable crashworthiness prediction. Without considering the fracture behavior, component fracture cannot be predicted and subsequently the crash energy absorbed by the fractured component can be over-estimated. In full vehicle simulations, failure to predict component fracture sometimes leads to less predicted intrusion. In this paper, the feasibility of using computer simulations in predicting fracture during crash deformation is studied.

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

Pushbuttons, knobs and plastic faceplates in automotive interiors are constantly exposed to chemicals such as sunscreen. In some instances, structural degradation of the plastic may occur with specific chemical agents and degradation can also be accelerated by high temperatures. A study of the propensity of commercial polycarbonate (PC) to craze and ultimately crack when exposed to sunscreen is outlined in this paper. Three-point bend testing per ASTM D3929 results in permissible bending strain limits for prolonged exposure to sunscreen at elevated temperatures. The paper outlines implementation details of these strain limits applied to a button surface, including finite element analyses identifying strain at the observed failure locations. Design considerations for related parts and products are also outlined.

Scuffing is a common source of failure for many mechanical components in automobiles. 8625 alloy steel is commonly used in camshafts, gears, piston pins, shafts, and splines. The purpose of the research is to study the scuffing resistance of non-treated, carburized, nitrocarburized, and carbonitrided 8625 alloy steels. The scuffing resistance of the 8625 alloy steels was determined through pin-on-disk tests. The hardness and microstructure of the disks were analyzed using electron microscopy to determine wear mechanisms for each surface treated steel. The wear mechanisms were then related to the scuff resistance of the various materials.